Complexation Studies of Zn2+, Cu2+, Co2+, Ni2+ and Cd2+ Ions with a Schiff Base Ligand

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Conductometric Studies of the Thermodynamics of Complexation of Zn2+, Ni2+, Co2+, Pb2+, Mn2+, Cu2+ Ions with 1,13-Bis(8-Quinolyl)-1,4,7,10,13-Pentaoxatridecane in Binary Solvent Mixtures

The complexation reaction between 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane (Kryptofix5) ligand with Zn2+, Ni2+, Co2+, Pb2+, Mn2+ and Cu2+ ions were studied conductometrically in different AcetoNitrile-NitroMethane (AN-NM) and AcetoNitrile-Methanol (AN-MeOH) mixtures. The formation constants of the resulting...

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Synthesis and Solution Complexation Studies of a new Schiff base Ligand

A new Schiff base ligand, 2,2'-{pyridine-2,6-diylbis[nitrilo(E)methylylidene]}bis(4 bromophenol),has been synthesized by reaction of the 2,6-diamino pyridine with 5-bromo salicylaldehyde at ethanolunder refluxing. The structure of the synthesized compound resulted from the IR, 1HNMR, MS andUV spectroscopy and elemental analysis data. Formation Constant (kf) value of it’s complexes withCu2+, Ni2...

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conductometric studies of the thermodynamics of complexation of zn2+, ni2+, co2+, pb2+, mn2+, cu2+ ions with 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane in binary solvent mixtures

the complexation reaction between 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane (kryptofix5) ligand with zn2+, ni2+, co2+, pb2+, mn2+ and cu2+ ions were studied conductometrically in different acetonitrile-nitromethane (an-nm) and acetonitrile-methanol (an-meoh) mixtures. the formation constants of the resulting 1:1 complexes were calculated from the computer fitting of the molar conductan...

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Interaction of Novel Ni2+, Cu2+ and VO2+ Complexes of a Tridentate Schiff Base Ligand with DNA, BSA and their Cytotoxic Activity

In this research, the interaction of [CuL(DMF)], [NiL(DMF)] and [VOL(DMF)] (where L = ((E)-4-((2-amino-5-nitrophenylimino)methyl)benzene-1,3-diol)) complexes derived from tridentate Schiff base ligand with bovine serum albumin (BSA) and DNA was investigated via electronic absorption and fluorescence spectroscopy. The Ultraviolet-Visible (UV-Vis) spectra exhibited an isosbestic point for the com...

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synthesis and solution complexation studies of a new schiff base ligand

a new schiff base ligand, 2,2'-{pyridine-2,6-diylbis[nitrilo(e)methylylidene]}bis(4 bromophenol),has been synthesized by reaction of the 2,6-diamino pyridine with 5-bromo salicylaldehyde at ethanolunder refluxing. the structure of the synthesized compound resulted from the ir, 1hnmr, ms anduv spectroscopy and elemental analysis data. formation constant (kf) value of it’s complexes withcu2+, ni2...

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ژورنال

عنوان ژورنال: Orbital - The Electronic Journal of Chemistry

سال: 2017

ISSN: 1984-6428

DOI: 10.17807/orbital.v9i4.1014